SCR system and method for the purging thereof

ABSTRACT

SCR system for treating the exhaust gases of an internal combustion engine, this system comprising a line for feeding a urea solution into the exhaust gases and a pump capable both of feeding the urea solution into the exhaust gases and of purging at least one part of the line by sucking a gas therethrough by means of a suction device, this system also comprising a control unit capable of activating and/or deactivating the operation of the pump and that of the suction device in a sequential manner in the course of one and the same purge procedure.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of and claims the benefit of priorityunder 35 U.S.C. §120 from U.S. Ser. No. 12/676,653 filed Mar. 5, 2010,which is a U.S. national stage application under 35 U.S.C. §371 ofInternational Application No. PCT/EP2008/062184 filed Sep. 12, 2008,which claims priority to French Patent Application No. 07577602 filedSep. 14, 2007, these applications being incorporated herein by referencein their entirety for all purposes.

TECHNICAL FIELD OF THE INVENTION

The present application relates to an SCR system and a method forpurging such a system.

BACKGROUND OF THE INVENTION

Legislations on vehicle and heavy goods vehicle emissions stipulate,amongst other things, a reduction in the release of nitrogen oxidesNO_(x) into the atmosphere. One known way to achieve this objective isto use the SCR (Selective Catalytic Reduction) process which enables thereduction of nitrogen oxides by injection of a reducing agent, generallyammonia, into the exhaust line. This ammonia may derive from thepyrolytic decomposition of an ammonia precursor solution, whoseconcentration may be the eutectic concentration. Such an ammoniaprecursor is generally a urea solution.

With the SCR process, the high levels of NO_(x) produced in the engineduring combustion at optimized efficiency are treated in a catalyst onexiting the engine. This treatment requires the use of the reducingagent at a precise concentration and of extreme quality. The solution isthus accurately metered and injected into the exhaust gas stream whereit is hydrolysed before converting the nitrogen oxide (NO_(x)) tonitrogen (N₂) and water (H₂O).

In order to do this, it is necessary to equip the vehicles with a tankcontaining an additive (generally urea) solution and also a device formetering the desired amount of additive and injecting it into theexhaust line.

Given that the aqueous urea solution generally used for this purpose(eutectic solution containing 32.5 wt % of urea) freezes at −11° C., itis necessary to provide a heating device to liquefy the solution inorder to be able to inject it into the exhaust line in the event ofstarting in freezing conditions.

Moreover, with a view to facilitating the operation, the re-starting ofthe system in case of freezing and to prevent the often flexible tubingthat transports the urea from bursting, it is advantageous to purge theconduits after operating the system. In particular, it is advantageousto purge the line connecting the additive tank to the injector (orinjection line) and the return line, where appropriate.

Several systems have been provided in the prior art for this purpose.

Thus, Application WO 2006/064028 in the name of the Applicant proposesan SCR system where purging of the line(s) takes place by sucking theexhaust gases through the injector using the pump of the system, whichfor this purpose either rotates in the opposite direction or isassociated with a valve that makes it possible to reverse the flow. Theadvantage of this system is its simplicity and the reduced number ofmodifications that must be made to it in order to add this function(this is because it suffices to choose a pump that rotates in bothdirections or to provide a 4-way valve in the system).

This document also mentions the fact that it is preferable not to purgedirectly after shutting off the engine as the gases might be too hot andmight damage certain parts of the system. For this purpose it recommendsa temperature control in order to adjust the time delay before purging.

However, it would appear that this problem is not, in reality, trulycritical (no doubt because as soon as the engine is shut off, thetemperature in the exhaust pipe drops rapidly) and that, in addition, itmay be prevented by choosing to suck up air from outside the exhaustpipe (and not the air/gases in said pipe). Conversely, if the purge isstarted immediately after the engine is shut off, there is a risk ofspraying urea into the exhaust pipe and/or over the catalyst. Thisphenomenon is capable of causing the premature ageing of the catalystand also corrosion problems in the exhaust pipe following the release ofammonia.

SUMMARY OF THE INVENTION

The present invention aims to solve this problem by providing a simpleand economic method for purging an SCR system where spraying urea overthe catalyst and/or into the silencer of the engine, once the latter isshut off, is avoided.

Hence, the present application relates to an SCR system for treating theexhaust gases of an internal combustion engine, this system comprising aline for feeding the urea solution into the exhaust gases and a pumpcapable both of feeding the urea solution into said exhaust gases and ofpurging at least one part of the line by sucking a gas therethrough bymeans of a suction device, this system also comprising a control unitcapable of activating and/or deactivating the operation of the pump andthat of the suction device in a sequential manner in the course of oneand the same purge procedure.

BRIEF DESCRIPTION OF THE DRAWINGS

For a detailed description of the preferred embodiments of theinvention, reference will now be made to the accompanying drawings inwhich:

FIG. 1 consists of a block diagram of a process according to severalvariants of the present invention applied to a suitable SCR system;

FIG. 2 illustrates the change in pressure at the outlet of a gear pumpand the logic that results therefrom in an SCR system; and

FIG. 3 illustrates an embodiment of a method for controlling the pumpwhich includes sending a single Pulse Width Modulation (PWM) signal to apump controller which only integrates a speed regulator, aProportional-Integral-Derivative (PID) or Proportional-Integral (PI)regulator being integrated into an Electronic Control Unit (ECU).

FIG. 4 illustrates an embodiment of the SCR system.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

The expression “SCR system” is understood to mean a system for thecatalytic reduction of the NO_(x) from the exhaust gases of an internalcombustion engine, preferably of a vehicle, using urea as a liquidammonia precursor. The present invention is advantageously applied todiesel engines, and in particular to the diesel engines of vehicles andparticularly preferably to the diesel engines of heavy goods vehicles.

The term “urea” is understood to mean any, generally aqueous, solutioncontaining urea. The invention gives good results with eutecticwater/urea solutions for which there is a quality standard: for example,according to the standard DIN 70070, in the case of the AdBlue® solution(commercial solution of urea), the urea content is between 31.8% and33.2% (by weight) (i.e. 32.5+/−0.7 wt %) hence an available amount ofammonia between 18.0% and 18.8%. The invention may also be applied tothe urea/ammonium formate mixtures, also in aqueous solution, sold underthe trade name Denoxium™ and of which one of the compositions(Denoxium-30) contains an equivalent amount of ammonia to that of theAdBlue® solution. The latter have the advantage of only freezing from−30° C. onwards (as opposed to −11° C.), but have the disadvantages ofcorrosion problems linked to the possible release of formic acid. Thepresent invention is particularly advantageous in the context ofeutectic water/urea solutions.

SCR systems generally comprise at least one tank for storing the ureasolution and also a set of components for feeding this to the exhaustgases and that generally comprises active elements such as a pump,filter, valve(s), urea feed conduits (or even urea return conduits insome cases). The method according to the invention enables thesecomponents to be purged by sucking gas through them so as to drive theurea solution that they contain back to the tank.

This is because, as explained in a co-pending application in the name ofthe Applicant, in freezing weather it is advantageous to purge thesecomponents in order to be able to defer the heating thereof (relative tothat of the tank) when the system is started up. It is also necessary topurge the system to avoid damaging the flexible tubing used to conveyurea from the tank to the injector.

According to the invention, this purge is carried out using the feedpump and a device that enables a gas (air or exhaust gas) to be suckedup. This device may be an injector or a purge valve. Preferably, thepurge procedure starts shortly after the engine is shut off.

The expression “purge procedure” is understood to mean the set ofoperations linked to the purge that are carried out as soon as theengine is shut off, this including an optional control to determinewhether or not it is necessary to purge the system. This is because,during short journeys the SCR system may not have started up (becausethe catalyst was not at the right temperature or because, in freezingweather, the heating of the system was not sufficient to start the pump)and it is then important not to purge the lines since they are empty(having been purged when the engine was shut off previously).

Therefore, according to one preferred variant of the invention, the SCRsystem has a connection with the ignition key. By means of thisconnection the status of the engine (running or shut off) iscommunicated to the system and the purge procedure is started as soon asthe engine is shut off using the ignition key.

The pump of the system according to the invention may be located in theurea tank (with the advantage of forming, with it, a compact andintegrated module) or, considering the corrosive environment, be locatedoutside of the urea tank. Its constituent materials will preferably bechosen from corrosion-resistant metals (especially certain grades ofstainless steel and aluminium). The use of copper, even for connectioncomponents, is undesirable.

Any type of pump may be suitable. The Applicant has obtained goodresults with a rotary positive-displacement pump of the gear pump typeand in particular, with such a magnetic drive pump (such as thatdescribed in Application FR 0756387 in the name of the Applicant, thecontent of which is, for this purpose, incorporated by reference in thepresent application). The speed of this pump is preferably driven asdescribed in Application PCT/EP2007/057066 in the name of the Applicant(the content of which is also, for this purpose, incorporated byreference in the present application).

The purge gas (air or exhaust gas) suction device may also be of anyknown type. It may, for example, be a valve or the injector used formetering. Generally, SCR systems comprise an injector at the end of thefeed line. In this case, either the suction valve is located very closeto this injector (in order to limit the unpurged length as much aspossible and/or to enable air to be sucked through the engine silencer,in which case the valve should be located in the exhaust pipe), or it isthe injector itself which acts as a suction device. In practice, it isoften sufficient to simply open the injector. However, when the injectoris governed by a control unit other than that of the SCR system (forexample, by that of the engine), the use of a valve or of any othersuction device directly controlled by the control unit of the SCR systemis generally called for (unless provision is made for a system ofcommunication between the two control units, which is sometimes morecomplicated and/or undesired). The control units mentioned above aregenerally electronic units or ECUs (Electronic Control Units).

In the system according to the invention, the control unit of the SCRsystem is such that it makes it possible to activate and/or deactivatethe operation of the pump and that of the suction device in a sequentialmanner.

Within the context of the invention, the term “operation” is understoodto mean operation in purge mode. While it is operating in “purge” modethe pump can either rotate in the reverse direction relative to itsnormal mode of operation (feed mode), or rotate in the same direction ifthe system comprises a valve that makes it possible to reverse the flows(e.g. 4-way valve as already mentioned previously). In other words,according to one preferred variant, in order that the system can bepurged effectively: either the pump is capable of rotating in twoopposite directions, or the system comprises a 4-way valve that makes itpossible to reverse the flow in the line without changing the directionof rotation of the pump.

According to one preferred variant of the invention, the operation ofthe pump in “purge” mode is only activated a certain time after the pumpoutlet pressure has dropped below a reference value. This is because, inparticular in the case of rotary positive-displacement pumps, thepressure decreases with the motor speed and only becomes low enough whenthis motor speed is almost at rest.

This sequenced activation may be carried out using a timer that enablesthe pump to be actuated at the end of a predetermined period and/orafter the pressure (p) has dropped below a reference value (p_(ref)),and makes it possible to open and close the device used for sucking airthrough the silencer.

Therefore, according to one preferred variant of the invention, the SCRsystem comprises a timer and a pressure sensor capable of measuring thepressure at the pump outlet. Preferably, this measurement is made inreal time, i.e. at regular intervals of the order of ms (milliseconds)for example, and the control unit is capable of detecting, in real time,the moment at which this pressure drops below a reference value and, atthis moment, of actuating the pump in “purge” mode and of starting thetimer which finally runs to the end of a given time interval, allowingthe air-suction device to open and close at predetermined times.

Alternatively, when the system does not comprise a pressure sensor, thetimer may be used for actuating the pump in “purge” mode at the end of apre-calibrated interval (which is determined experimentally) aftercutting the engine and then allowing the air-suction device to open andclose at predetermined times.

In these two variants, the operation of the pump in “purge” mode istherefore activated before that of the device that enables air or gas tobe sucked through the silencer in order to prevent urea from beingdischarged into the exhaust pipe and/or over the catalyst at the startof the purge (when the lines are full of urea). Generally, the timebetween the activation of the pump and that of the suction device isshort (typically of the order of ms) in order to avoid generating toohigh a vacuum in the section of the line located between the pump andthe suction device (which could cause it to implode (collapse),especially in the case of lines made of plastic).

The SCR system according to the invention may comprise a non-returndevice that prevents liquid from entering into these elements once theyhave been purged. This non-return device is preferably located betweenthe pump and the urea tank, and most particularly preferably at thejunction of the purged elements with the tank.

In particular, it may be a non-return device as described in ApplicationFR 0756388 in the name of the Applicant (the content of which isincorporated by reference in the present application). In a system thatincorporates such a device, the pump, said device and a urea filter arecombined in a compact module, the filter at least partly surrounding thepump and the non-return device being an integral part of a commonhousing that surrounds the filter and at least one part of the pump.

This compact module is preferably integrated into an immerged base platein the liquid tank and the common housing comprises a cover and a lowerpart such that:

-   -   the lower part consists of a sealed enclosure which comprises a        substantially cylindrical wall equipped with a base and moulded        from one part with the base plate and also a cover assembled in        a sealed manner with this cylindrical wall, on which the filter        rests and through which the rotation axle is inserted in a        sealed manner; and    -   the cover surrounds the filter and the mechanical element and is        attached via a screw and nut connection to the sealed enclosure.

This cover has the shape of a bell having at least one opening in itslower part and it is positioned so as to create an annular cavitybetween its inner surface and the outer surface of the enclosure/filterwhere the liquid can be sucked up through its lower opening.

In particular in a system with a non-return device it is advantageousfor the aforementioned timer to be capable of deactivating the operationof the pump before that of the suction device (typically a few msbefore). This is because, in the opposite case, the pump would becapable of creating a vacuum in the section of line connecting it to thesuction device and this section could then fill with liquid once thepump stops, despite the presence of the non-return device.

The period of time that the pump operates in “purge” mode is preferablylong enough to purge all the liquid between the injector and thenon-return device. In the variant with a bell-shaped cover describedabove, this period of time is preferably long enough to discharge allthe liquid present in the system including under the bell (so as to keepthe filter dry). This period of time varies from one system to anotherdepending, in particular, on the length of the lines. These values aredetermined during calibrations (prior tests).

In view of the foregoing, FIG. 4 illustrates a non-binding embodiment ofthe above-described SCR system. The SCR system includes: a tank (1); aninjection line (2); an injector (3); an exhaust pipe (4) through whichexhaust gases flow; a pump (5); a pressure sensor (6); and a timer (7).

The present invention also relates to a method for purging an SCR systemcomprising a pump both for feeding a urea solution into said exhaustgases and for purging the system by sucking a gas therethrough by meansof a suction device, according to which the operation of the pump andthat of the suction device are activated and/or deactivated in asequential manner in the course of one and the same purge procedure.

Preferably, this method uses a “real time” electronic control system. Inother words: a system capable of responding to given events in setperiods of time.

The preferred variants described above in the “system” part of theinvention are for application within the context of the method accordingto the invention.

In particular, according to one particularly preferred variant of theinvention, the purge procedure comprises, successively and in order, thefollowing steps:

-   1. the engine shut-off is detected;-   2. it is checked whether or not the pump has operated while the    engine was running;-   3. if the pump was not operated, the procedure is stopped;-   3′. if the pump was operated, the procedure is continued by carrying    out, successively and in order, the following steps:-   4′. the pressure at the pump outlet is measured and when this is    below a reference value (p_(ref)), a timer is started (t=0)-   5′. when the timer detects the end of a predetermined time interval    (t1), it makes the pump rotate in purge mode;-   6′. when the timer detects the end of a predetermined time interval    (t1+t2), the suction device is opened;-   7′. when the timer detects the end of a predetermined time interval    (t1+t2+t3), the pump is stopped;-   8′. when the timer detects the end of a predetermined time interval    (t1+t2+t3+t4), the suction device is closed.

Detection of whether or not the pump has operated may be carried out,for example, by automatically setting a parameter to “1” when the enginehas run under normal temperature conditions and by setting it to “1”under freezing conditions only if the engine has run for a long enoughperiod for the system to be hot and for the pump to have been able tostart.

The method according to the invention is illustrated, in a non-limitingmanner, by appended FIGS. 1 and 2. FIG. 1 consists of a block diagram ofa process according to several variants of the present invention appliedto a suitable SCR system; and FIG. 2 illustrates the change in pressureat the outlet of a gear pump and the logic that results therefrom in anSCR system.

The process illustrated in FIG. 1 can be applied to an SCR systemcomprising a feed pump; a sensor of the pressure at its outlet; anelectronic control unit (ECU) driven by a real-time system using asingle timer; and a valve for sucking up air and/or exhaust gases.

This process is initiated by the detection of contact with the vehicleengine being cut (KO or Key Off). This therefore causes the purgeprocedure to be started (EPM or Enable Purge Mode).

From this moment, the ECU will check whether the pump has operated (seeabove) or not (CP or Control Pump).

If the pump has not run (negative response to the question PW? or PumpWorked?), the purge procedure is stopped (DPM or Disable Purge Mode).

If on the other hand the response to the question (PW?) is positive, thepurge procedure is continued and the ECU will repeatedly compare thepressure value read by the sensor to a reference pressure (RCP or Read &Compare Pressure). As soon as this pressure is reached (positiveresponse to the question p<p_(ref)?), the ECU starts a timer (ST or SetTimer) that sets the time to zero (t=0).

At the end of an interval t1 (which may be equal to zero), the feed pumpof the system is rotated in reverse (SPR or Start Pump Reverse).

At the end of an additional interval t2 (i.e. t=t1+t2 on the timer atthis moment), the suction valve is opened (OV or Open Valve).

At the end of an additional interval t3 (i.e. t=t1+t2+t3 on the timer atthis moment), the pump is stopped (SP or Stop Pump).

Finally, at the end of an additional interval t4 (i.e. t=t1+t2+t3+t4 onthe timer at this moment), the suction valve is closed (CV or CloseValve) and the purge procedure is stopped (DPM or Disable Purge Mode).

In FIG. 2, in its upper part, it is possible to see the shape of thecurve of the pressure at the outlet of a gear pump as a function oftime.

When the pump starts up a pressure increase peak is seen (whichtypically culminates at around 9 bar in the SCR system in question),then stabilization at the operating pressure (around 5 bar in thiscase). When the pump is turned off, the pressure gradually falls inorder to drop below a reference value (equal to 0.2 bar in thisexample), but with fluctuations over a certain period of time.

The lower figures represent the logic of the phenomenon: the firstillustrates, in a boolean manner, the event “pressure below thereference value” (p<p ref); the second, the event “contact broken” (KOor Key Off); and the third, the event “starting of the pump in purgemode” (SP or Start Purge).

As can be seen from these figures, it is advantageous to defer the startof the purge for a certain period of time before starting the purge inorder to ensure that the pressure is low enough to prevent urea frombeing discharged into the exhaust pipe and/or over the catalyst. Thistime may either be measured effectively by a pressure sensor (caseillustrated) or have been obtained experimentally by calibration tests.The pressure fluctuations illustrated in the upper part of FIG. 2, whichare minor and are not capable of leading to discharges, are ignored dueto the use of a timer as explained above.

The way the pump can be controlled to either feed the solution, to bestopped or to function in purge mode can be as described in applicationWO 2008/087153 in the name of the Applicant. The method for controllingthe pump described in that document uses a single PWM signal having aduty cycle that varies in function of the desired operation conditionsfor the pump. In the embodiment pictured in the figure of thatapplication, the pump controller includes a speed controller and a PIDregulator in order to adapt the speed of the pump to the desired outputpressure.

FIG. 3 shows another embodiment of that method, applying the same ideaof sending a single PWM signal to the pump controller, but where saidcontroller only integrates the speed regulator, the PID regulator (oreven preferably: a PI regulator) being integrated into the ECU.

As shown in this figure, the ECU is able of receiving four signals: astop signal (ST), a reverse mode signal (R), a working (measured)pressure signal (MP) and a reference pressure signal (RP). The PI(D)regulator which is integrated into it, compares the 2 two last signals(MP, RP) and emits a PWM signal giving a rotational speed information(RS) on a scale from 0 to 100 corresponding respectively to the minimumand maximum rotational speed of the pump. The ECU then computes the(ST), (R) and (RS) signals into one single PWM signal (PWMCmd) whichinstructs the pump to either stop, rotate in reverse mode or rotate inforward mode at a given speed.

In the embodiment of FIG. 1 of the above mentioned WO'153 application,the ECU only receives three signals (ST, R and reference pressure) andthese are directly computed in the PWM signal sent to the pumpcontroller.

The invention claimed is:
 1. A Selective Catalytic Reduction (SCR)system for treating the exhaust gases of an internal combustion engine,the system comprising: a line that feeds a urea solution into theexhaust gases; a pump that both feeds the urea solution into saidexhaust gases and purges at least one part of the line by sucking a gasthrough the at least one part by a suction device, the pump including anoutlet; a timer; a pressure sensor that measures the pressure at thepump outlet; and an electronic control unit configured to: activate anddeactivate operation of the pump and operation of the suction device ina sequential manner in the course of one and a same purge procedure; andstart the timer and actuate the pump in a purge mode if the pressuremeasured by the pressure sensor drops below a reference value, whereinthe timer is configured to control the suction device to open and closeat predetermined times after actuating the pump.
 2. The SCR systemaccording to claim 1, wherein the electronic control unit is furtherconfigured to activate the purge after a certain period when the engineis shut off.
 3. The SCR system according to claim 1, wherein the pump isa rotary positive-displacement pump of a gear pump type.
 4. The SCRsystem according to claim 1, further comprising: an injector thatinjects the urea solution into the exhaust gases, wherein the suctiondevice is either a valve that sucks up air or exhaust gases that islocated close to the injector, or is constituted by the injector itself.5. The SCR system according to claim 1, wherein either the pump rotatesin two opposite directions, or the system comprises a 4-way valve thatreverses flow in the line without changing the direction of rotation ofthe pump.
 6. The SCR system according to claim 1, wherein the electroniccontrol unit is further configured to deactivate the operation of thepump before deactivating the operation of the suction device.
 7. ASelective Catalytic Reduction (SCR) system for treating the exhaustgases of an internal combustion engine, the system comprising: a linethat feeds a urea solution into the exhaust gases; a pump that bothfeeds the urea solution into said exhaust gases and purges at least onepart of the line by sucking a gas through the at least one part by asuction device, the pump including an outlet; a timer; a pressure sensorthat measures the pressure at the pump outlet; and an electric controlunit configured to: activate and deactivate operation of the pump andoperation of the suction device in a sequential manner in the course ofone and a same purge procedure; start the timer if the pressure measuredby the pressure sensor drops below a reference value; and actuate thepump by the electronic control unit in a purge mode at the end of apredetermined time interval detected by said timer, wherein the timer isconfigured to open and close the suction device at predetermined timesafter actuating the pump.